Brock Samson being Hardcore
Brock giving a henchmen bad news
If these two scenes don't sell you on Venture Brothers... well you are just missing out. Brock Samson is just one of the many AWESOME (yes it needs to be in all caps) characters in Venture Brothers. I can't say enough good things about this show, even these clips don't capture the perfect humor that is The Venture Brothers.
Venture Brothers is on Teletoon in the Canada, Adult Swim in the US, and both season 1 and 2 are out on DVD. Of course it is also floating around on pseudo legal streaming sites on the internet. So go forth and enjoy.